The purpose of this report is to <,locument the sensitivity of the drift-scale thermal-hydrologic- chemical (THC) seepage model (SNL 2007 [DIRS 177404]) to heterogeneities in permeability and capillarity, which could affect predicted fluxes and chemistries of water and gases seeping into the emplacement drifts. This report has been developed following Technical Work Plan for: Revision of Model Reports for Near-Field and In-Drift Water Chemistry (SNL 2007 [DIRS 179287]).

The purpose of this engineering calculation is to provide the chemical composition for the Department of Energy (DOE) Savannah River Site (SRS) High-Level Waste (HLW) glass. Since the glass is to be co-disposed with other DOE spent nuclear fuels (SNFs) in the Monitored Geologic Repository (MGR), its chemical composition is needed for the design of the co-disposal canisters and waste packages in term of criticality and degradation.

This report was developed in accordance with the requirements in Technical Work Plan for Postclosure Waste Form Modeling (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA).

In this study, the long-term geochemical behavior of waste package (WP), containing Pu-ceramic, was modeled. The ceramic under consideration contains Ti, U, Pu, Gd and Hf in a pyrochlore structure; the Gd and Hf stabilize the mineral structure, but are also intended to provide criticality control. The specific study objectives were to determine:
1) the extent to which criticality control material, suggested for this WP design, will remain in the WP after corrosion/dissolution of the initial package configuration (such that it can be effective in preventing criticality), and

The Monitored Geologic Repository (MGR) Waste Package Operations (WPO) of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Shippingport Pressurized Water Reactor (PWR) (Ref. 1). The Shippingport PWR SNF has been considered for disposal at the proposed Yucca Mountain site.