In this study, the long-term geochemical behavior of waste package (WP), containing Pu-ceramic, was modeled. The ceramic under consideration contains Ti, U, Pu, Gd and Hf in a pyrochlore structure; the Gd and Hf stabilize the mineral structure, but are also intended to provide criticality control. The specific study objectives were to determine:
1) the extent to which criticality control material, suggested for this WP design, will remain in the WP after corrosion/dissolution of the initial package configuration (such that it can be effective in preventing criticality), and

The purpose of this calculation is to perform a parametric study to determine the effects of fission product leaching, assembly collapse, and iron oxide loss (Me203) on the reactivity of a waste package (WP) containing mixed oxide (MOX) spent nuclear fuel (SNF). Previous calculations (CRWMS M&O 1998a) have shown that the criticality control features of the WP are adequate to prevent criticality of a flooded WP for all the enrichment/ burnup pairs expected for the MOX SNF.

This analysis is prepared by the Mined Geologic Disposal System (MODS) Waste Package Development (WPD) department to provide an evaluation of the criticality potential within a waste package having some or all of its contents degraded by corrosion and removal of neutron absorbers. This analysis is also intended to provide an estimate of the consequences of any internal criticality, particularly in terms of any increase in radionuclide inventory. These consequence estimates will be used as part of the WPD input to the Total System Performance Assessment.

The effects of radiation on the corrosion of various metals and alloys, particularly with respect to in-reactor processes, has been discussed by a number of authors (Shoesmith and King 1998, p.2). Shoesmith and King (1998) additionally discuss the effects of radiation of the proposed Monitored Geologic Repository (MGR) Waste Package (WP) materials. Radiation effects on the corrosion of metals and alloys include, among other things, radiolysis of local gaseous and aqueous environments lead to the fixation of nitrogen as NO, NO2, and especially HN03 (Reed and Van Konynenburg 1988, pp.

This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development (WPD) department to provide an evaluation of the criticality potential within a waste package having some or all of its contents degraded by corrosion and removal of neutron absorbers. This analysis is also intended to provide an estimate of the consequences of any internal criticality, particularly in terms of any increase in radionuclide inventory. These consequence estimates will be used as part of the WPD input to the Total System Performance Assessment.

The purpose of these calculations is to characterize the criticality safety concerns for the storage of Fast Flux Test Facility (FFTF) nuclear fuel in a Department of Energy spent nuclear fuel (DOE SNF) canister in a co-disposal waste package. These results will be used to support the analysis that will be done to demonstrate concept viability related to use in the Monitored Geologic Repository (MGR) environment.

The purpose of this calculation is to perform a parametric study to determine the effects of fission product leaching, assembly collapse, and iron oxide loss on the reactivity of a waste package (WP) containing mixed oxide (MOX) spent nuclear fuel (SNF). Previous calculations (CRWMS M&O 1998a) have shown that the criticality control features of the WP are adequate to prevent criticality of a flooded WP for all the enrichment/burnup pairs expected for the MOX SNF.

The purpose of this calculation is to characterize the criticality aspect of the codisposal of TRIGA (Training, Research, Isotopes, General Atomic) reactor spent nuclear fuel (SNF) with Savannah River Site (SRS) high-level waste (HLW). The TRIGA SNF is loaded into a Department of Energy (DOE) standardized SNF canister which is centrally positioned inside five-canister defense SRS HLW waste package (WP). The objective of the calculation is to investigate the criticality issues for the WP containing the five SRS HLW and DOE SNF canisters in various stages of degradation.