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Radiolytic Specie Generation from Internal Waste Package Criticality

The effects of radiation on the corrosion of various metals and alloys, particularly with respect to in-reactor processes, has been discussed by a number of authors (Shoesmith and King 1998, p. 2). Shoesmith and King (1998) additionally discuss the effects of radiation on the proposed Monitored Geologic Repository (MGR) Waste Package (WP) materials. Radiation effects on the corrosion of metals and alloys include, among other things, radiolysis of the local gaseous and aqueous environment to produce both oxidizing and reducing radicals.
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