Skip to main content

Qualification of Thermodynamic Data for Geochemical Modeling of Mineral–Water Interactions in Dilute Systems

This report is developed from Technical Work Plan for: Thermodynamic Databases for Chemical Modeling (BSC 2006 [DIRS 177885]). The purpose of this analysis report is to update the thermochemical database data0.ymp.R4 (Output DTN: SN0410T0510404.002). Various data have been added, corrected, or corroborated, partly in response to four Condition Reports (CRs): CR 6489, CR 6731, CR 7542, and CR 7756. The most notable changes are a general revision of phosphate data to achieve consistency with the recommendations from the Committee on Data for Science and Technology (CODATA) (Cox. et al.

Second Waste Package Probabilistic Criticality Analysis: Generation and Evaluation of Internal Criticality Configurations

This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development (WPD) department to provide an evaluation of the criticality potential within a waste package having some or all of its contents degraded by corrosion and removal of neutron absorbers. This analysis is also intended to provide an estimate of the consequences of any internal criticality, particularly in terms of any increase in radionuclide inventory. These consequence estimates will be used as part of the WPD input to the Total System Performance Assessment.

Radiolytic Specie Generation from Internal Waste Package Criticality

The effects of radiation on the corrosion of various metals and alloys, particularly with respect to in-reactor processes, has been discussed by a number of authors (Shoesmith and King 1998, p. 2). Shoesmith and King (1998) additionally discuss the effects of radiation on the proposed Monitored Geologic Repository (MGR) Waste Package (WP) materials. Radiation effects on the corrosion of metals and alloys include, among other things, radiolysis of the local gaseous and aqueous environment to produce both oxidizing and reducing radicals.

Bias Determination for DOE Nuclear Fuels

The purpose of this calculation is to establish the relative change in the effective neutron multiplication factor (keff) due to the use of MCNP unique identifiers (ZAIDs) in Nuclear Criticality Calculations for Canister-Based Facilities - DOE SNF (Reference 2.2.1, Attachment 3, MCNP inputs.zip) that are different to the ZAIDs used in the Analysis of Critical Benchmark Experiments and Critical Limit Calculation for DOE SNF (Reference 2.2.5, Table 5-3).

Analysis of Mechanisms for Early Waste Package / Drip Shield Failure

The purpose of this analysis is to evaluate the types of defects or imperfections that could occur in a waste package or a drip shield and potentially lead to its early failure, and to estimate a probability of undetected occurrence for each type. An early failure is defined as the through-wall penetration of a waste package or drip shield due to manufacturing or handling-induced defects, at a time earlier than would be predicted by mechanistic degradation models for a defect-free waste package or drip shield.

Criticality Evaluation of Intact and Degraded PWR WPs Containing MOX SNF

The purpose of this calculation is to perform criticality evaluations for mixed oxide spent nuclear fuel (MOX SNF) in 12 and 21 Pressurized Water Reactor (PWR) waste packages (WPs) for both intact and degraded configurations.
The MOX assembly design considered in previous studies on Pu disposition in commercial reactors is based on the Westinghouse (W) 17x17 Vantage 5 assembly (Ref. 7.2). Depletion analyses of four Pu enrichment and burnup (expressed as gigawatt days/metric ton heavy metal; GWd/MTHM) combinations were performed in Reference 7.4. These are:

Preclosure Criticality Safety Analysis

The means to prevent and control criticality must be addressed as part of the Preclosure Safety Analysis (PCSA) required for compliance with 10 CFR Part 63 [DIRS 180319], where the preclosure period covers the time prior to permanent closure activities. This technical report presents the nuclear criticality safety evaluation that documents the achievement of this objective.

EQ6 Calculations for Chemical Degradation of Pu-Ceramic Waste Packages

In this study, the long-term geochemical behavior of waste package (WP), containing Pu-ceramic, was modeled. The ceramic under consideration contains Ti, U, Pu, Gd and Hf in a pyrochlore structure; the Gd and Hf stabilize the mineral structure, but are also intended to provide criticality control. The specific study objectives were to determine:
1) the extent to which criticality control material, suggested for this WP design, will remain in the WP after corrosion/dissolution of the initial package configuration (such that it can be effective in preventing criticality), and

Sequoyah Unit 2 CRC Depletion Calculations

The purpose of this calculation is to document the Sequoyah Unit 2 pressurized water reactor (PWR) fuel depletion calculations performed as part of the commercial reactor critical (CRC) evaluation program. The CRC evaluations support the development and validation of the neutronics models used for criticality analyses involving commercial spent nuclear fuel in a geologic repository.

Disclaimer: Note that this page contains links to external sites. When leaving the CURIE site, please note that the U.S. Department of Energy and Pacific Northwest National Laboratory do not control or endorse the content or ads on these sites.