This analysis provides information necessary for total system performance assessment (TSPA) for the license application (LA) to include the excess U.S. Department of Energy (DOE) plutonium in the form of mixed oxide (MOX) spent nuclear fuel and lanthanide borosilicate (LaBS) glass. This information includes the additional radionuclide inventory due to MOX spent nuclear fuel and LaBS glass and the analysis that shows that the TSPA models for commercial spent nuclear fuel (CSNF) and high-level waste (HLW) degradation are appropriate for MOX spent nuclear fuel and LaBS glass, respectively.

The purpose of this calculation is to develop an estimate of the isotopic content as a function of time for mixed oxide (MOX) spent nuclear fuel (SNF) assemblies in a Westinghouse pressurized water reactor (PWR). These data will be used as source data for criticality, thermal, and radiation shielding evaluations of waste package (WP) designs for MOX assemblies in the Monitored Geologic Repository (MGR).

As part of the plutonium waste form development and down-select process, repository analyses have been conducted to evaluate the long-term performance of these forms for repository acceptance. Intact and degraded mode criticality analysis of the mixed oxide (MOX) spent fuel is presented in Volume I, while Volume II presents the evaluations of the waste form containing plutonium immobilized in a ceramic matrix.

The purpose of the material degradation and release (MDR) model is to predict the fate of the waste package materials, specifically the retention or mobilization of the radionuclides and the neutron-absorbing material as a function of time after the breach of a waste package during the 10,000 years after repository closure. The output of this model is used directly to assess the potential for a criticality event inside the waste package due to the retention of the radionuclides combined with a loss of the neutron-absorbing material.

The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating long-term waste package performance in the total system performance assessment (TSPA). The waste package design for the license application is a double-wall waste package placed underneath a protective drip shield (SNL 2007 [DIRS 179394]; SNL 2007 [DIRS 179354]). The WPOB will be constructed of Alloy 22 (UNS N06022) (SNL 2007 [DIRS 179567], Section 4.1.1.6), a highly corrosion-resistant nickel-based alloy.

As part of the plutonium waste form development and down-select process, repository analyses have been conducted to evaluate the long-term performance of these forms for repository acceptance. Intact and degraded mode criticality analysis of the mixed oxide (MOX) spent fuel is presented in Volume I, while Volume II presents the evaluations of the waste form containing plutonium immobilized in a ceramic matrix.

The purpose of this calculation is to perform a parametric study to determine the effects of fission product leaching, assembly collapse, and iron oxide loss (Me203) on the reactivity of a waste package (WP) containing mixed oxide (MOX) spent nuclear fuel (SNF). Previous calculations (CRWMS M&O 1998a) have shown that the criticality control features of the WP are adequate to prevent criticality of a flooded WP for all the enrichment/ burnup pairs expected for the MOX SNF.

The purpose of this calculation is to perform a parametric study to determine the effects of fission product leaching, assembly collapse, and iron oxide loss on the reactivity of a waste package containing mixed oxide spent nuclear fuel. Previous calculations (CRWMS M&O 1998a) have shown that the criticality control features of the waste package are adequate to prevent criticality of a flooded WP for all the enrichment/burnup pairs expected for the MOX SNF.

Stress corrosion cracking (SCC) is one of the most common corrosion-related causes for premature breach of metal structural components. SCC is the initiation and propagation of cracks in structural components due to three factors that must be present simultaneously (Jones 1992 [DIRS 169906], Section 8.1): metallurgical susceptibility, critical environment, and sustained tensile stresses.

This report was developed in accordance with the requirements in Technical Work Plan for Postclosure Waste Form Modeling (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA).

The purpose of this calculation is to perform criticality evaluations for mixed oxide spent nuclear fuel (MOX SNF) in 12 and 21 Pressurized Water Reactor (PWR) waste packages (WPs) for both intact and degraded configurations.
The MOX assembly design considered in previous studies on Pu disposition in commercial reactors is based on the Westinghouse (W) 17x17 Vantage 5 assembly (Ref. 7.2). Depletion analyses of four Pu enrichment and burnup (expressed as gigawatt days/metric ton heavy metal; GWd/MTHM) combinations were performed in Reference 7.4. These are:

The objective of this calculation is to perform additional degraded mode criticality evaluations of the Department of Energy's (DOE) Fast Flux Test Facility (FFTF) Spent Nuclear Fuel (SNF) codisposed in a 5-Defense High-Level Waste (5-DHLW) Waste Package (WP). The scope of this calculation is limited to the most reactive degraded configurations of the codisposal WP with an almost intact Ident-69 container (breached and flooded but otherwise non-degraded) containing intact FFTF SNF pins.

The purpose of this calculation is to evaluate the transient behavior and consequences of a worst- case criticality event involving intact pressurized water reactor (PWR) mixed-oxide (MOX) spent nuclear fuel (SNF) in a degraded basket configuration inside a 21 PWR waste package (WP). This calculation will provide information necessary for demonstrating that the consequences of a worst-case criticality event involving intact PWR MOX SNF are insignificant in their effect on the overall radioisotopic inventory and on the integrity of the repository.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

The repository design includes a drip shield (BSC 2004 [DIRS 168489]) that provides protection for the waste package both as a barrier to seepage water contact and a physical barrier to potential rockfall.
The purpose of the process-level models developed in this report is to model dry oxidation, general corrosion, and localized corrosion of the drip shield plate material, which is made of Ti Grade 7. This document is prepared ·according to Technical Work Plan For: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package (BSC 2004 [DIRS 171583]).

This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development Department (WPDD) to compare the criticality potential of Westinghouse 17x17 mixed oxide (MOX) PWR fuel with the Design Basis spent nuclear fuel (SNF) analyzed previously (Ref. 5.1, 5.2). The basis of comparison will be the conceptual design Multi- Purpose Canister (MPC) PWR waste package concepts.

The purpose of this analysis is to evaluate the types of defects or imperfections that could occur in a waste package or a drip shield and potentially lead to its early failure, and to estimate a probability of undetected occurrence for each type. An early failure is defined as the through-wall penetration of a waste package or drip shield due to manufacturing or handling-induced defects, at a time earlier than would be predicted by mechanistic degradation models for a defect-free waste package or drip shield.

Hydrogen-induced cracking is characterized by the decreased ductility and fracture toughness of a material due to the absorption of atomic hydrogen in the metal crystal lattice. Corrosion is the source of hydrogen generation. For the current design of the engineered barrier without backfill, hydrogen-induced cracking may be a concern because the titanium drip shield can be galvanically coupled to rock bolts (or wire mesh), which may fall onto the drip shield, thereby creating conditions for hydrogen production by electrochemical reaction.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

There are more than 250 forms of U.S. Department of Energy (DOE)-owned spent nuclear fuel (SNF). Due to the variety of the spent nuclear fuel, the National Spent Nuclear Fuel Program (NSNFP) has designated nine representative fuel groups for disposal criticality analyses based on fuel matrix, primary fissile isotope, and enrichment. Fast Flux Test Facility (FFTF) fuel has been designated as the representative fuel for the mixed-oxide (MOX) fuel group which is a mixture of uranium and plutonium oxides.

The purpose of this calculation is to perform criticality evaluations for mixed oxide spent nuclear fuel in 12 and 21 pressurized water reactor waste packages for both intact and degraded configurations. The MOX assembly design considered in previous studies on Pu disposition in commercial reactors is based on the Westinghouse 17x17 Vantage 5 assembly (Ref. 7.2). Depletion analyses of four Pu enrichment and burnup(expressed as gigawatt days/metric ton heavy metal; GWd/MTHM)) combinations were performed in Ref. 7.4.

The purpose of this calculation is to perform a parametric study to determine the effects of fission product leaching, assembly collapse, and iron oxide loss on the reactivity of a waste package (WP) containing mixed oxide (MOX) spent nuclear fuel (SNF). Previous calculations (CRWMS M&O 1998a) have shown that the criticality control features of the WP are adequate to prevent criticality of a flooded WP for all the enrichment/burnup pairs expected for the MOX SNF.