The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments.

The objective of this calculation is to evaluate the probability of flooding a waste package with seepage water. Disruptive events can affect the Engineered Barrier System (EBS) components and have the potential to allow an advective flow of seepage water to reach the waste package. The advective and diffusive flow paths into the waste package have the potential to result in water accumulation inside the waste package, which in turn can lead to a potentially critical configuration. This calculation will evaluate the following:

This study is prepared by the Mined Geologic Disposal System (MODS) Waste Package Development Department (WPDD) to provide input to a separate evaluation on the probablility of criticality in the far- field environment. These calculations are performed in sufficient detail to provide conservatively bounding configurations to support separate probabilistic analyses.

This report documents the development and validation of the in-drift precipitates/salts (IDPS) process model. The IDPS process model is a geochemical model designed to predict the postclosure effects of evaporation and deliquescence on the chemical composition of water within the Engineered Barrier System (EBS) in support of the total system performance assessment (TSPA). Application of the model in support of TSPA is documented in Engineered Barrier System: Physical and Chemical Environment (BSC 2005 [DIRS 175083]).

The purpose of this model report is to describe the evolution of the physical and chemical environmental conditions within the waste emplacement drifts of the repository, including the drip shield and waste package surfaces. This report documents the development of a new process-level model, the near-field chemistry (NFC) model, and develops two abstraction models.

This technical report provides an updated summary of the waste package (WP) external criticalityrelated
risk of the plutonium disposition ceramic waste form, which is being developed and
evaluated by the Office of Fissile Materials Disposition of the U.S. Department of Energy (DOE).
The ceramic waste form consists of Pu immobilized in ceramic disks, which would be embedded
in High-Level Waste (HLW) glass in the HLW glass disposal canisters, known as the "can-incanister"

The objective of this analysis is to characterize the criticality safety aspects of a degraded Department of Energy spent nuclear fuel (DOE-SNF) canister containing Massachusetts Institute of Technology (MIT) or Oak Ridge Research (ORR) fuel in the Five-Pack Defense High-Level Waste (DHLW) waste package to demonstrate concept viability related to use in the Mined Geologic Disposal System (MGDS) environment for the postclosure time frame.