The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments.

The objective of this calculation is to evaluate the probability of flooding a waste package with seepage water. Disruptive events can affect the Engineered Barrier System (EBS) components and have the potential to allow an advective flow of seepage water to reach the waste package. The advective and diffusive flow paths into the waste package have the potential to result in water accumulation inside the waste package, which in turn can lead to a potentially critical configuration. This calculation will evaluate the following:

This study is prepared by the Mined Geologic Disposal System (MODS) Waste Package Development Department (WPDD) to provide input to a separate evaluation on the probablility of criticality in the far- field environment. These calculations are performed in sufficient detail to provide conservatively bounding configurations to support separate probabilistic analyses.

The purpose of this activity is to develop a representative “limiting” axial burnup profile for pressurized water reactors (PWRs), which would encompass the isotopic axial variations caused by different assembly irradiation histories, and produce conservative isotopics with respect to criticality. The effect that the low burnup regions near the ends of spent fuel have on system reactivity is termed the “end-effect”. This calculation will quantify the end-effects associated with Pressurized Water Reactor (PWR) fuel assemblies emplaced in a hypothetical 21 PWR waste package.

The purpose of this calculation is to develop axial profiles for estimating the axial variation in burnup of a boiling water reactor (BWR) assembly spent nuclear fuel (SNF) given the average burnup of an assembly. A discharged fuel assembly typically exhibits higher burnup in the center and lower burnup at the ends of the assembly. Criticality safety analyses taking credit for SNF burnup must account for axially varying burnup relative to calculations based on uniformly distributed assembly average burnup due to the under-burned tips.

This report documents the development and validation of the in-drift precipitates/salts (IDPS) process model. The IDPS process model is a geochemical model designed to predict the postclosure effects of evaporation and deliquescence on the chemical composition of water within the Engineered Barrier System (EBS) in support of the total system performance assessment (TSPA). Application of the model in support of TSPA is documented in Engineered Barrier System: Physical and Chemical Environment (BSC 2005 [DIRS 175083]).

The purpose of this model report is to describe the evolution of the physical and chemical environmental conditions within the waste emplacement drifts of the repository, including the drip shield and waste package surfaces. This report documents the development of a new process-level model, the near-field chemistry (NFC) model, and develops two abstraction models.

The purpose of this activity is to develop a representative “limiting” axial burnup profile for pressurized water reactors (PWRs), which would encompass the isotopic axial variations caused by different assembly irradiation histories, and produce conservative isotopics with respect to

This calculation compares results from criticality evaluations for a 21-assembly pressurized water reactor (PWR) waste package based on 12 axial burnup profile representations for commercial spent nuclear fuel (SNF) assemblies. The burnup profiles encompass the axial variations caused by different fuel assembly irradiation histories in a commercial PWR, including end effects, and the concomitant effect on reactivity in the waste package. The bounding axial burnup profiles in Table T of reference 6.3 are used for this analysis.