The Monitored Geologic Repository (MGR) Waste Package Operations (WPO) of the Civilian Radioactive Waste Management System Management and Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of Pu-ceramic waste forms. The Pu- ceramic (Refs. 1 and 2) is designed to immobilize excess plutonium from weapons production, and has been considered for disposal at the potential Yucca Mountain site.

This analysis is prepared by the Mined Geologic Disposal System (MODS) Waste Package Development (WPD) department to provide an evaluation of the criticality potential within a waste package having some or all of its contents degraded by corrosion and removal of neutron absorbers. This analysis is also intended to provide an estimate of the consequences of any internal criticality, particularly in terms of any increase in radionuclide inventory. These consequence estimates will be used as part of the WPD input to the Total System Performance Assessment.

The Monitored Geologic Repository Waste Package Operations of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Navy (Refs. 1 and , 2). The Navy SNF has been considered for disposal at the potential Yucca Mountain site. For some waste packages, the containment may breach (Ref. 3), allowing the influx of water. Water in the waste package may moderate neutrons, increasing the likelihood of a criticality event within the waste package.

The Monitored Geologic Repository (MGR) Waste Package Operations (WPO) of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Shippingport Pressurized Water Reactor (PWR) (Ref. 1). The Shippingport PWR SNF has been considered for disposal at the proposed Yucca Mountain site.

The purpose of this analysis is to provide input on the criticality potential of various degraded configurations to an analysis on the probability of a criticality event in a Pressurized Water Reactor (PWR) Advanced Uncanistered Fuel (AUCF) Waste Package (WP).

The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating long-term waste package performance in the total system performance assessment (TSPA). The waste package design for the license application is a double-wall waste package placed underneath a protective drip shield (SNL 2007 [DIRS 179394]; SNL 2007 [DIRS 179354]). The WPOB will be constructed of Alloy 22 (UNS N06022) (SNL 2007 [DIRS 179567], Section 4.1.1.6), a highly corrosion-resistant nickel-based alloy.

The Monitored Geologic Repository (MGR) Waste Package Operations (WPO) of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Emico Fermi Atomic Power Plant (Ref. 1). The Fermi fuel has been considered for disposal at the potential Yucca Mountain site.

Stress corrosion cracking (SCC) is one of the most common corrosion-related causes for premature breach of metal structural components. SCC is the initiation and propagation of cracks in structural components due to three factors that must be present simultaneously (Jones 1992 [DIRS 169906], Section 8.1): metallurgical susceptibility, critical environment, and sustained tensile stresses.

In this study, the long-term geochemical behavior of waste package (WP), containing Pu-ceramic, was modeled. The ceramic under consideration contains Ti, U, Pu, Gd and Hf in a pyrochlore structure; the Gd and Hf stabilize the mineral structure, but are also intended to provide criticality control. The specific study objectives were to determine:
1) the extent to which criticality control material, suggested for this WP design, will remain in the WP after corrosion/dissolution of the initial package configuration (such that it can be effective in preventing criticality), and

Fuel from the Fast Flux Test Facility ' (FFTF) has been considered for disposal at the proposed

The Monitored Geologic Repository (MGR) Waste Package Project of the BSC Management and Operating Contractor for the Department of Energy's Office of Civilian Radioactive Waste Management performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Enrico Fermi Reactor owned by the DOE (Ref. 9). The Fermi SNF has been considered for disposal at the proposed Yucca Mountain site.

The Monitored Geologic Repository Waste Package Operations of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Training, Research, Isotopes, General Atomics (TRIGA) reactor (Ref. 1). The TRIGA SNF has been considered for disposal at the potential Yucca Mountain site.

The Monitored Geologic Repository (MGR) Waste Package Department of the Civilian Radioactive Waste Management System Management & Operating contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Shippingport Light Water Breeder Reactor (LWBR) (Ref. 1). The Shippingport LWBR SNF has been considered for disposal at the potential Yucca Mountain site.

The repository design includes a drip shield (BSC 2004 [DIRS 168489]) that provides protection for the waste package both as a barrier to seepage water contact and a physical barrier to potential rockfall.
The purpose of the process-level models developed in this report is to model dry oxidation, general corrosion, and localized corrosion of the drip shield plate material, which is made of Ti Grade 7. This document is prepared ·according to Technical Work Plan For: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package (BSC 2004 [DIRS 171583]).

The purpose of this analysis report is to develop the summary cladding degradation abstraction that will be used in the Total System Performance Assessment for the License Application (TSPA-LA). Most civilian commercial nuclear fuel is encased in Zircaloy cladding. The analysis addressed in this report is intended to describe the postulated condition of commercial Zircaloy-clad fuel as a function of postclosure time after it is placed in the repository.

This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development (WPD) department to describe the latest version of the probabilistic criticality analysis methodology and its application to the entire commercial waste stream of commercial pressurized water reactor (PWR) spent nuclear fuel (SNF) expected to be emplaced in the repository. The purpose of this particular application is to evaluate the 21 assembly PWR absorber plate waste package (WP) with respect to degraded mode criticality performance.

The purpose of this analysis is to evaluate the types of defects or imperfections that could occur in a waste package or a drip shield and potentially lead to its early failure, and to estimate a probability of undetected occurrence for each type. An early failure is defined as the through-wall penetration of a waste package or drip shield due to manufacturing or handling-induced defects, at a time earlier than would be predicted by mechanistic degradation models for a defect-free waste package or drip shield.

Hydrogen-induced cracking is characterized by the decreased ductility and fracture toughness of a material due to the absorption of atomic hydrogen in the metal crystal lattice. Corrosion is the source of hydrogen generation. For the current design of the engineered barrier without backfill, hydrogen-induced cracking may be a concern because the titanium drip shield can be galvanically coupled to rock bolts (or wire mesh), which may fall onto the drip shield, thereby creating conditions for hydrogen production by electrochemical reaction.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

This report is developed from Technical Work Plan for: Thermodynamic Databases for Chemical Modeling (BSC 2006 [DIRS 177885]). The purpose of this analysis report is to update the thermochemical database data0.ymp.R4 (Output DTN: SN0410T0510404.002). Various data have been added, corrected, or corroborated, partly in response to four Condition Reports (CRs): CR 6489, CR 6731, CR 7542, and CR 7756. The most notable changes are a general revision of phosphate data to achieve consistency with the recommendations from the Committee on Data for Science and Technology (CODATA) (Cox. et al.

The effects of radiation on the corrosion of various metals and alloys, particularly with respect to in-reactor processes, has been discussed by a number of authors (Shoesmith and King 1998, p.2). Shoesmith and King (1998) additionally discuss the effects of radiation of the proposed Monitored Geologic Repository (MGR) Waste Package (WP) materials. Radiation effects on the corrosion of metals and alloys include, among other things, radiolysis of local gaseous and aqueous environments lead to the fixation of nitrogen as NO, NO2, and especially HN03 (Reed and Van Konynenburg 1988, pp.