This paper draws on my experience as a reviewer of the scientific programs and performance assessments of the geological repository for transuranic waste at the Waste Isolation Pilot Plant in New Mexico and the proposed repository for spent nuclear fuel and high-level waste at Yucca Mountain in Nevada. In addition, I have served on numerous committees of the National Research Council that have addressed many aspects of nuclear waste management.

The purpose of this engineering calculation is to estimate the frequency of misloading spent nuclear fuel (SNF) assemblies that would result in exceeding the criticality design basis of a waste package (WP). This type of misload - a reactivity misload - results from the incorrect placement of one or more fuel assemblies into a waste package such that the criticality controls do not match the required controls for the fuel assemblies. An actual criticality event can not occur in a WP unless a moderator (e.g. water) is present.

The purpose of the material degradation and release (MDR) model is to predict the fate of the waste package materials, specifically the retention or mobilization of the radionuclides and the neutron-absorbing material as a function of time after the breach of a waste package during the 10,000 years after repository closure. The output of this model is used directly to assess the potential for a criticality event inside the waste package due to the retention of the radionuclides combined with a loss of the neutron-absorbing material.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

The objective of this calculation is to perform intact and degraded mode criticality evaluations of the Department of Energy's (DOE) N Reactor Spent Nuclear Fuel codisposed in a 2-Defense High-Level Waste (2-DHLW)/2-Multi-Canister Overpack (MCO) Waste Package (WP) and emplaced in a monitored geologic repository (MGR) (see Attachment I). The scope of this calculation is limited to the determination of the effective neutron multiplication factor (k{sub eff}) for both intact and degraded mode internal configurations of the codisposal waste package.

This report presents the analyses and results for the potential occurrence of external criticality events which could result from plutonium waste forms emplaced in a geologic repository similar to the one being developed at Yucca Mountain. The analyses evaluate both the MOX spent fuel and the immobilized plutonium waste forms in a repository if the waste package has degraded and if the fissile material has migrated to the invert and out into the far-field.

This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development (WPD) department to provide an evaluation of the criticality potential within a waste package having some or all of its contents degraded by corrosion and removal of neutron absorbers. This analysis is also intended to provide an estimate of the consequences of any internal criticality, particularly in terms of any increase in radionuclide inventory. These consequence estimates will be used as part of the WPD input to the Total System Performance Assessment.

The United States Department of Energy (DOE) is developing a postclosure methodology for criticality analysis to evaluate disposal of commercial spent nuclear fuel and other high-level waste in a geologic repository. A topical report on the postclosure disposal criticality analysis methodology is scheduled to be submitted to the United States Nuclear Regulatory Commission (NRC) for formal review in 1998 (to be verified). This technical report is being issued to describe the current status of the postclosure methodology development effort.

This report is developed from Technical Work Plan for: Thermodynamic Databases for Chemical Modeling (BSC 2006 [DIRS 177885]). The purpose of this analysis report is to update the thermochemical database data0.ymp.R4 (Output DTN: SN0410T0510404.002). Various data have been added, corrected, or corroborated, partly in response to four Condition Reports (CRs): CR 6489, CR 6731, CR 7542, and CR 7756. The most notable changes are a general revision of phosphate data to achieve consistency with the recommendations from the Committee on Data for Science and Technology (CODATA) (Cox. et al.