The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments.

The objective of these calculations is to perform intact and degraded mode criticality evaluations of the Department of Energy's (DOE) Three Mile Island- Unit 2 (TMI-2) spent nuclear fuel (SNF) in canisters. This analysis evaluates codisposal in a 5-Defense High-Level Waste (5-DHLW/DOE SNF) Long Waste Package (Civilian Radioactive Waste Management System Management and Operating Contractor [CRWMS M&O] 2000b, Attachment V), which is to be placed in a potential monitored geologic repository (MGR).

Criticality safety analysis devoted to spent-fuel storage and transportation has to be conservative in order to be sure no accident will ever happen. In the spent-fuel storage field, the assumption of freshness has been used to achieve the conservative aspect of criticality safety procedures. Nevertheless, after being irradiated in a reactor core, the fuel elements have obviously lost part of their original reactivity. The concept of taking into account this reactivity loss in criticality safety analysis is known as burnup credit.

The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments.

Performance objectives for the geologic repository operations area through permanent closure in 10 CFR 63.111 identify compliance with regulatory dose limits for workers and members of the public as a design objective. The purpose of this design calculation is to determine direct radiation dose consequences for Category 1 and 2 event sequences. It does not include worker dose assessment for recovery operations following Category 1 event sequences.