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Geochemistry Model Validation Report: Material Degradation and Release Model
Geochemistry Model Validation Report: Material Degradation and Release Model
The purpose of the material degradation and release (MDR) model is to predict the fate of the waste package materials, specifically the retention or mobilization of the radionuclides and the neutron-absorbing material as a function of time after the breach of a waste package during the 10,000 years after repository closure. The output of this model is used directly to assess the potential for a criticality event inside the waste package due to the retention of the radionuclides combined with a loss of the neutron-absorbing material.
General Corrosion and Localized Corrosion of Waste Package Outer Barrier
General Corrosion and Localized Corrosion of Waste Package Outer Barrier
The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating long-term waste package performance in the total system performance assessment (TSPA). The waste package design for the license application is a double-wall waste package placed underneath a protective drip shield (SNL 2007 [DIRS 179394]; SNL 2007 [DIRS 179354]). The WPOB will be constructed of Alloy 22 (UNS N06022) (SNL 2007 [DIRS 179567], Section 4.1.1.6), a highly corrosion-resistant nickel-based alloy.
Report on intact and Degraded Criticality for Selected Plutonium Waste Forms in a. Geologic Repository, Volume I: MOX SNF
Report on intact and Degraded Criticality for Selected Plutonium Waste Forms in a. Geologic Repository, Volume I: MOX SNF
As part of the plutonium waste form development and down-select process, repository analyses have been conducted to evaluate the long-term performance of these forms for repository acceptance. Intact and degraded mode criticality analysis of the mixed oxide (MOX) spent fuel is presented in Volume I, while Volume II presents the evaluations of the waste form containing plutonium immobilized in a ceramic matrix.
Evaluation of Internal Criticality of the Plutonium Disposition MOX SNF Waste Form
Evaluation of Internal Criticality of the Plutonium Disposition MOX SNF Waste Form
The purpose of this calculation is to perform a parametric study to determine the effects of fission product leaching, assembly collapse, and iron oxide loss on the reactivity of a waste package containing mixed oxide spent nuclear fuel. Previous calculations (CRWMS M&O 1998a) have shown that the criticality control features of the waste package are adequate to prevent criticality of a flooded WP for all the enrichment/burnup pairs expected for the MOX SNF.
SAS2H Analysis of Radiochemical Assay Samples from Yankee Rowe PWR Reactor
SAS2H Analysis of Radiochemical Assay Samples from Yankee Rowe PWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied to future depletion calculations using SAS2H in which no measurements are available.
SAS2H Analysis of Radiochemical Assay Samples from Trino Vercelles PWR Reactor
SAS2H Analysis of Radiochemical Assay Samples from Trino Vercelles PWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied to future depletion calculations using SAS2H in which no measurements are available.
Stress Corrosion Cracking of Waste Package Outer Barrier and Drip Shield Materials
Stress Corrosion Cracking of Waste Package Outer Barrier and Drip Shield Materials
Stress corrosion cracking (SCC) is one of the most common corrosion-related causes for premature breach of metal structural components. SCC is the initiation and propagation of cracks in structural components due to three factors that must be present simultaneously (Jones 1992 [DIRS 169906], Section 8.1): metallurgical susceptibility, critical environment, and sustained tensile stresses.
In-Package Chemistry Abstraction
In-Package Chemistry Abstraction
This report was developed in accordance with the requirements in Technical Work Plan for Postclosure Waste Form Modeling (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA).
SAS2H Analysis of Radiochemical Assay Samples from Cooper BWR Reactor
SAS2H Analysis of Radiochemical Assay Samples from Cooper BWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied to future depletion calculations using SAS2H in which no measurements are available.
SAS2H Analysis of Radiochemical Assay Samples from Calvert Cliffs PWR Reactor
SAS2H Analysis of Radiochemical Assay Samples from Calvert Cliffs PWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied to future depletion calculations using SAS2H in which no measurements are available.
SAS2H Analysis of Radiochemical Assay Samples from Obrigheim PWR Reactor
SAS2H Analysis of Radiochemical Assay Samples from Obrigheim PWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied to future depletion calculations using SAS2H in which no measurements are available.
Analysis of Dust Deliquescence for FEP Screening
Analysis of Dust Deliquescence for FEP Screening
The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).
General Corrosion and Localized Corrosion of the Drip Shield
General Corrosion and Localized Corrosion of the Drip Shield
The repository design includes a drip shield (BSC 2004 [DIRS 168489]) that provides protection for the waste package both as a barrier to seepage water contact and a physical barrier to potential rockfall.
The purpose of the process-level models developed in this report is to model dry oxidation, general corrosion, and localized corrosion of the drip shield plate material, which is made of Ti Grade 7. This document is prepared ·according to Technical Work Plan For: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package (BSC 2004 [DIRS 171583]).
Canister Handling Facility Criticality Safety Calculations
Canister Handling Facility Criticality Safety Calculations
This design calculation revises and updates the previous criticality evaluation for the canister handling, transfer and staging operations to be performed in the Canister Handling Facility (CHF) documented in BSC (Bechtel SAIC Company) 2004 (DIRS 167614).
Analysis of Mechanisms for Early Waste Package / Drip Shield Failure
Analysis of Mechanisms for Early Waste Package / Drip Shield Failure
The purpose of this analysis is to evaluate the types of defects or imperfections that could occur in a waste package or a drip shield and potentially lead to its early failure, and to estimate a probability of undetected occurrence for each type. An early failure is defined as the through-wall penetration of a waste package or drip shield due to manufacturing or handling-induced defects, at a time earlier than would be predicted by mechanistic degradation models for a defect-free waste package or drip shield.
Hydrogen-Induced Cracking of the Drip Shield
Hydrogen-Induced Cracking of the Drip Shield
Hydrogen-induced cracking is characterized by the decreased ductility and fracture toughness of a material due to the absorption of atomic hydrogen in the metal crystal lattice. Corrosion is the source of hydrogen generation. For the current design of the engineered barrier without backfill, hydrogen-induced cracking may be a concern because the titanium drip shield can be galvanically coupled to rock bolts (or wire mesh), which may fall onto the drip shield, thereby creating conditions for hydrogen production by electrochemical reaction.
Analysis of Dust Deliquescence for FEP Screening
Analysis of Dust Deliquescence for FEP Screening
The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).
SAS2H Analysis of Radiochemical Assay Sam les from H.B. Robinson PWR Reactor
SAS2H Analysis of Radiochemical Assay Sam les from H.B. Robinson PWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied to future depletion calculations using SAS2H in which no measurements are available.
SAS2H Analysis of Radiochemical Assay Samples from Mihama PWR Reactor
SAS2H Analysis of Radiochemical Assay Samples from Mihama PWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied to future depletion calculations using SAS2H in which no measurements are available.
SAS2H Analysis of Radiochemical Assay Samples from Turkey Point PWR Reactor
SAS2H Analysis of Radiochemical Assay Samples from Turkey Point PWR Reactor
The purpose of this design analysis is to determine the accuracy of the SAS2H module of SCALE 4.3 in predicting isotopic concentrations of spent fuel assemblies. The objective is to develop a methodology for modeling assemblies similar to those evaluated within this analysis and to establish the consistency of SAS2H predictions. The results of this analysis may then be applied·to future depletion calculations using SAS2H in which no measurements are available. ·
Sensitivity Study of Reactivity Consequences to Waste Package Egress Area
Sensitivity Study of Reactivity Consequences to Waste Package Egress Area
The criticality consequence analysis for pressurized water reactor (PWR) waste packages (WP)
(Civilian Radioactive Waste Management System [CRWMS] Management and Operating
Contractor [M&O] 1997) focused on results obtained by maximizing postulated rates of
reactivity insertion to assure no synergistic reactions could occur among waste packages from
hypothetical criticality events. Other variables potentially influencing the criticality
consequences were held constant during the above referenced analysis. One of those variables
44-BWR WASTE PACKAGE LOADING CURVE EVALUATION
44-BWR WASTE PACKAGE LOADING CURVE EVALUATION
The objective of this calculation is to evaluate the required minimum burnup as a function of initial boiling water reactor (BWR) assembly enrichment that would permit loading of spent nuclear fuel into the 44 BWR waste package configuration as provided in Attachment IV. This calculation is an application of the methodology presented in ''Disposal Criticality Analysis Methodology Topical Report'' (YMP 2003). The scope of this calculation covers a range of enrichments from 0 through 5.0 weight percent (wt%) U-235, and a burnup range of 0 through 40 GWd/MTU.
TEV Collision with an Emplaced 5-DHLW/DOE SNF Short Co-Disposal Waste Package
TEV Collision with an Emplaced 5-DHLW/DOE SNF Short Co-Disposal Waste Package
The objective of this calculation is to determine the structural response of the 5-DHLW/DOE (Defense High Level Waste/Department of Energy) SNF (Spent Nuclear Fuel) Short Co-disposal Waste Package (WP) when subjected (while in the horizontal orientation emplaced in the drift) to a collision by a loaded (with WP) Transport and Emplacement Vehicle (TEV) due to an over-run. The scope of this calculation is limited to reporting the calculation results in terms of maximum total stress intensities (SIs) in the outer corrosion barrier (OCB).
Enrico Fermi Fast Reactor Spent Nuclear Fuel Criticality Calculations: Degraded Mode
Enrico Fermi Fast Reactor Spent Nuclear Fuel Criticality Calculations: Degraded Mode
The objective of this calculation is to characterize the nuclear criticality safety concerns
associated with the codisposal of the Department of Energy’s (DOE) Enrico Fermi (EF) Spent
Nuclear Fuel (SNF) in a 5-Defense High-Level Waste (5-DHLW) Waste Package (WP) and
placed in a Monitored Geologic Repository (MGR). The scope of this calculation is limited to
the determination of the effective neutron multiplication factor (keff) for the degraded mode
internal configurations of the codisposal WP. The results of this calculation and those of Ref. 8