The purpose of the material degradation and release (MDR) model is to predict the fate of the waste package materials, specifically the retention or mobilization of the radionuclides and the neutron-absorbing material as a function of time after the breach of a waste package during the 10,000 years after repository closure. The output of this model is used directly to assess the potential for a criticality event inside the waste package due to the retention of the radionuclides combined with a loss of the neutron-absorbing material.

The Monitored Geologic Repository Waste Package Operations of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Navy (Refs. 1 and , 2). The Navy SNF has been considered for disposal at the potential Yucca Mountain site. For some waste packages, the containment may breach (Ref. 3), allowing the influx of water. Water in the waste package may moderate neutrons, increasing the likelihood of a criticality event within the waste package.

A methodology for performing and applying nuclear criticality safety calculations, for PWR spent nuclear fuel (SNF) packages with actinide-only burnup credit, is described. The changes in the U-234, U-235, U-236, U-238, Pu-238, Pu-239, Pu-240, Pu-241, Pu-242, and Am-241 concentration with burnup are used in burnup credit criticality analyses. No credit for fission product neutron absorbers is taken. The methodology consists of five major steps. (1) Validate a computer code system to calculate isotopic concentrations of SNF created during burnup in the reactor core and subsequent decay.

A methodology for performing and applying nuclear criticality safety calculations, for PWR spent nuclear fuel (SNF) packages with actinide-only burnup credit, is described. The changes in the U-234, U-235, U-236, U-238, Pu-238, Pu-239, Pu-240, Pu-241, Pu-242, and Am-241 concentration with burnup are used in burnup credit criticality analyses. No credit for fission product neutron absorbers is taken. The methodology consists of five major steps. (1) Validate a computer code system to calculate isotopic concentrations of SNF created during burnup in the reactor core and subsequent decay.

The Monitored Geologic Repository (MGR) Waste Package Operations (WPO) of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Shippingport Pressurized Water Reactor (PWR) (Ref. 1). The Shippingport PWR SNF has been considered for disposal at the proposed Yucca Mountain site.

The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating long-term waste package performance in the total system performance assessment (TSPA). The waste package design for the license application is a double-wall waste package placed underneath a protective drip shield (SNL 2007 [DIRS 179394]; SNL 2007 [DIRS 179354]). The WPOB will be constructed of Alloy 22 (UNS N06022) (SNL 2007 [DIRS 179567], Section 4.1.1.6), a highly corrosion-resistant nickel-based alloy.

Presented at the NEI Used Fuel Management Conference, St. Petersburg, FL, May 7-9, 2013

Stress corrosion cracking (SCC) is one of the most common corrosion-related causes for premature breach of metal structural components. SCC is the initiation and propagation of cracks in structural components due to three factors that must be present simultaneously (Jones 1992 [DIRS 169906], Section 8.1): metallurgical susceptibility, critical environment, and sustained tensile stresses.

This report was developed in accordance with the requirements in Technical Work Plan for Postclosure Waste Form Modeling (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA).

The Monitored Geologic Repository (MGR) Waste Package Project of the BSC Management and Operating Contractor for the Department of Energy's Office of Civilian Radioactive Waste Management performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Enrico Fermi Reactor owned by the DOE (Ref. 9). The Fermi SNF has been considered for disposal at the proposed Yucca Mountain site.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

The Monitored Geologic Repository Waste Package Operations of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Training, Research, Isotopes, General Atomics (TRIGA) reactor (Ref. 1). The TRIGA SNF has been considered for disposal at the potential Yucca Mountain site.

The Monitored Geologic Repository (MGR) Waste Package Department of the Civilian Radioactive Waste Management System Management & Operating contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Shippingport Light Water Breeder Reactor (LWBR) (Ref. 1). The Shippingport LWBR SNF has been considered for disposal at the potential Yucca Mountain site.

The repository design includes a drip shield (BSC 2004 [DIRS 168489]) that provides protection for the waste package both as a barrier to seepage water contact and a physical barrier to potential rockfall.
The purpose of the process-level models developed in this report is to model dry oxidation, general corrosion, and localized corrosion of the drip shield plate material, which is made of Ti Grade 7. This document is prepared ·according to Technical Work Plan For: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package (BSC 2004 [DIRS 171583]).

The purpose of this analysis is to evaluate the types of defects or imperfections that could occur in a waste package or a drip shield and potentially lead to its early failure, and to estimate a probability of undetected occurrence for each type. An early failure is defined as the through-wall penetration of a waste package or drip shield due to manufacturing or handling-induced defects, at a time earlier than would be predicted by mechanistic degradation models for a defect-free waste package or drip shield.

Hydrogen-induced cracking is characterized by the decreased ductility and fracture toughness of a material due to the absorption of atomic hydrogen in the metal crystal lattice. Corrosion is the source of hydrogen generation. For the current design of the engineered barrier without backfill, hydrogen-induced cracking may be a concern because the titanium drip shield can be galvanically coupled to rock bolts (or wire mesh), which may fall onto the drip shield, thereby creating conditions for hydrogen production by electrochemical reaction.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).