This “Technical Evaluation Report on the Content of the U.S. Department of Energy’s Yucca Mountain License Application; Postclosure Volume: Repository Safety After Permanent Closure” (TER Postclosure Volume) presents information on the NRC staff’s review of DOE’s Safety Analysis Report (SAR), provided on June 3, 2008, as updated by DOE on February 19, 2009. The NRC staff also reviewed information DOE provided in response to NRC staff’s requests for additional information and other information that DOE provided related to the SAR.

This analysis provides information necessary for total system performance assessment (TSPA) for the license application (LA) to include the excess U.S. Department of Energy (DOE) plutonium in the form of mixed oxide (MOX) spent nuclear fuel and lanthanide borosilicate (LaBS) glass. This information includes the additional radionuclide inventory due to MOX spent nuclear fuel and LaBS glass and the analysis that shows that the TSPA models for commercial spent nuclear fuel (CSNF) and high-level waste (HLW) degradation are appropriate for MOX spent nuclear fuel and LaBS glass, respectively.

As part of the plutonium waste form development and down-select process, repository analyses have been conducted to evaluate the long-term performance of these forms for repository acceptance. Intact and degraded mode criticality analysis of the mixed oxide (MOX) spent fuel is presented in Volume I, while Volume II presents the evaluations of the waste form containing plutonium immobilized in a ceramic matrix.

The purpose of the material degradation and release (MDR) model is to predict the fate of the waste package materials, specifically the retention or mobilization of the radionuclides and the neutron-absorbing material as a function of time after the breach of a waste package during the 10,000 years after repository closure. The output of this model is used directly to assess the potential for a criticality event inside the waste package due to the retention of the radionuclides combined with a loss of the neutron-absorbing material.

The purpose of this analysis is to provide an initial radionuclide inventory (in grams per waste package) and associated uncertainty distributions for use in the Total System Performance Assessment for the License Application (TSPA-LA) in support of the license application for the repository at Yucca Mountain, Nevada. This document is intended for use in postclosure analysis only.

The means to prevent and control criticality must be addressed as part of the Preclosure Safety Analysis (PCSA) required for compliance with 10 CFR Part 63 [DIRS 180319], where the preclosure period covers the time prior to permanent closure activities. This technical report presents the nuclear criticality safety evaluation that documents the achievement of this objective.

The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating long-term waste package performance in the total system performance assessment (TSPA). The waste package design for the license application is a double-wall waste package placed underneath a protective drip shield (SNL 2007 [DIRS 179394]; SNL 2007 [DIRS 179354]). The WPOB will be constructed of Alloy 22 (UNS N06022) (SNL 2007 [DIRS 179567], Section 4.1.1.6), a highly corrosion-resistant nickel-based alloy.

The purpose of this report is to document calculations of the number of waste packages that could be damaged in a potential future igneous event intersecting a repository at YuccaMountain. The analyses include disruption from an igneous intrusion and from an igneous eruption. The analyses also support the evaluation of the potential consequences from a future event as part of the total system performance assessment (TSPA) for the license application for the Yucca Mountain Project.

Stress corrosion cracking (SCC) is one of the most common corrosion-related causes for premature breach of metal structural components. SCC is the initiation and propagation of cracks in structural components due to three factors that must be present simultaneously (Jones 1992 [DIRS 169906], Section 8.1): metallurgical susceptibility, critical environment, and sustained tensile stresses.

This report was developed in accordance with the requirements in Technical Work Plan for Postclosure Waste Form Modeling (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA).

The objective of Calculation of Isotopic Bias and Uncertainty for BWR SNF is to quantify the computational bias and uncertainty in the multiplication factor (keff) to be used for Boiling Water Reactor (BWR) spent nuclear fuel (SNF) burn-up credit. The scope of this bias and uncertainty determination covers 38 different radiochemical assay (RCA) spent fuel samples from 14 different fuel assemblies that were irradiated in four different BWRs. The irradiated fuel samples evaluated span an enrichment range of 2.53 weight percent U-235 through 3.95 weight percent U-235.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

The repository design includes a drip shield (BSC 2004 [DIRS 168489]) that provides protection for the waste package both as a barrier to seepage water contact and a physical barrier to potential rockfall.
The purpose of the process-level models developed in this report is to model dry oxidation, general corrosion, and localized corrosion of the drip shield plate material, which is made of Ti Grade 7. This document is prepared ·according to Technical Work Plan For: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package (BSC 2004 [DIRS 171583]).

The objective of the Limerick Unit 1 Radiochemical Assay Comparisons to SAS2H Calculations is to determine the accuracy of the SAS2H control module of the baselined modular code system SCALE, Version 4.4A (STN: 10129-4.4A-00), in predicting the isotopic concentrations of spent fuel, and to quantify the overall effect that the differences between the calculated and measured isotopic concentrations have on the system reactivity. The scope of this calculation covers eight different spent fuel samples from a fuel assembly that was irradiated in the Limerick Unit 1 boiling water reactor (BWR).

The purpose of this analysis report is to develop the summary cladding degradation abstraction that will be used in the Total System Performance Assessment for the License Application (TSPA-LA). Most civilian commercial nuclear fuel is encased in Zircaloy cladding. The analysis addressed in this report is intended to describe the postulated condition of commercial Zircaloy-clad fuel as a function of postclosure time after it is placed in the repository.

The purpose of this analysis is to evaluate the types of defects or imperfections that could occur in a waste package or a drip shield and potentially lead to its early failure, and to estimate a probability of undetected occurrence for each type. An early failure is defined as the through-wall penetration of a waste package or drip shield due to manufacturing or handling-induced defects, at a time earlier than would be predicted by mechanistic degradation models for a defect-free waste package or drip shield.

Hydrogen-induced cracking is characterized by the decreased ductility and fracture toughness of a material due to the absorption of atomic hydrogen in the metal crystal lattice. Corrosion is the source of hydrogen generation. For the current design of the engineered barrier without backfill, hydrogen-induced cracking may be a concern because the titanium drip shield can be galvanically coupled to rock bolts (or wire mesh), which may fall onto the drip shield, thereby creating conditions for hydrogen production by electrochemical reaction.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

The purpose of this methods report is to document: (1) the origin, and the methods used in the development of a comprehensive list of features, events, and/or processes (FEPs) that could potentially affect the postclosure performance of the Yucca Mountain disposal system; (2) the methodology and guidance used to screen FEPs for inclusion or exclusion from Total System Performance Assessment for the License Application (TSPA-LA) analysis; (3) the methodology and guidance used to create scenario classes; and (4) compliance with NUREG-1804 (NRC 2003.

EPRI has discovered several aspects of the U.S Department of Energy (DOE) proposed design and operation of the Yucca Mountain repository that—if implemented as described in the license application (LA)—could result in unnecessary occupational health and safety risk to workers involved with repository-related activities. This report identifies key DOE conservatisms and focuses on the occupational risk consequences of the DOE's approach to the repository design, performance assessment, and operation.