The purpose of this report, and the information contained in the associated computerized data bases, is to establish the DOE/OCRWM reference characteristics of the radioactive waste materials that may be accepted by DOE for emplacement in the mined geologic disposal system as developed under the Nuclear Waste Policy Act of 1982. This report provides relevant technical data for use by DOE and its supporting contractors and is not intended to be a policy document.

The purpose of this calculation is to develop an estimate of the isotopic content as a function of time for mixed oxide (MOX) spent nuclear fuel (SNF) assemblies in a Westinghouse pressurized water reactor (PWR). These data will be used as source data for criticality, thermal, and radiation shielding evaluations of waste package (WP) designs for MOX assemblies in the Monitored Geologic Repository (MGR).

The "Summary Report of SNF Isotopic Comparisons for the Disposal Criticality Analysis Methodology" contains a summary of the analyses that compare SNF measured isotopic concentrations (radiochemical assays) to calculated SNF isotop~c concentrations (SAS2H module ·orScale4.3). The results of these analyses are used to support the validation of the isotopic models for spent commercial light water reactor (LWR) fuel.

The Disposal Criticality Analysis Methodology Topical Report (YMP 2003) presents the methodology for evaluating potential criticality situations in the monitored geologic repository. As stated in the referenced Topical Report, the detailed methodology for performing the disposal criticality analyses will be documented in model reports. Many of the models developed in support of the Topical Report differ from the definition of models as given in the Office of Civilian Radioactive Waste Management procedure AP-SIII.10Q, Models, in that they are procedural, rather than mathematical.

This analysis is prepared by the Mined Geologic Disposal System (MODS) Waste Package Development (WPD) department to provide an evaluation of the criticality potential within a waste package having some or all of its contents degraded by corrosion and removal of neutron absorbers. This analysis is also intended to provide an estimate of the consequences of any internal criticality, particularly in terms of any increase in radionuclide inventory. These consequence estimates will be used as part of the WPD input to the Total System Performance Assessment.

As part of the plutonium waste form development and down-select process, repository analyses have been conducted to evaluate the long-term performance of these forms for repository acceptance. Intact and degraded mode criticality analysis of the mixed oxide (MOX) spent fuel is presented in Volume I, while Volume II presents the evaluations of the waste form containing plutonium immobilized in a ceramic matrix.

The Office of Civilian Radioactive Waste Management (OCRWM) is responsible for all spent fuels and high-level wastes (HLW) that will eventually be disposed of in a geologic repository. The purpose of this document, and the information contained in the associated computerized data bases and supporting technical reports, is to provide the technical characteristics of the radioactive waste materials that will (or may) be accepted by DOE for interim storage in an MRS or emplacement in a repository as developed under the Nuclear Waste Policy Act Amendment of 1987.

The objective of these calculations is to perform intact and degraded mode criticality evaluations of the Department of Energy's (DOE) Three Mile Island- Unit 2 (TMI-2) spent nuclear fuel (SNF) in canisters. This analysis evaluates codisposal in a 5-Defense High-Level Waste (5-DHLW/DOE SNF) Long Waste Package (Civilian Radioactive Waste Management System Management and Operating Contractor [CRWMS M&O] 2000b, Attachment V), which is to be placed in a potential monitored geologic repository (MGR).

The Monitored Geologic Repository Waste Package Operations of the Civilian Radioactive Waste Management System Management & Operating Contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Navy (Refs. 1 and , 2). The Navy SNF has been considered for disposal at the potential Yucca Mountain site. For some waste packages, the containment may breach (Ref. 3), allowing the influx of water. Water in the waste package may moderate neutrons, increasing the likelihood of a criticality event within the waste package.

This report evaluates the potential for directly disposing of licensed commercial Dual Purpose
Canisters (DPCs) inside waste package overpacks without reopening. The evaluation considers
the principal features of the DPC designs that have been licensed by the Nuclear Regulatory
Commission (NRC) as these relate to the current designs of waste packages and as they relate to
disposability in the repository. Where DPC features appear to compromise future disposability,
those changes that would improve prospective disposability are identified.

In the past, criticality analysis of pressurized water reactor (PWR) fuel stored in racks and casks has assumed that the fuel is fresh with the maximum allowable initial enrichment. If credit is allowed for fuel burnup in the design of casks that are used in the transport of spent light water reactor fuel to a repository, the increase in payload can lead to a significant reduction in the cost of transport and a potential reduction in the risk to the public. A portion of the work has been performed at Oak Ridge National Laboratory (ORNL) in support of the U.S.

This report has been prepared by an ad-hoc Working Group (WG) formed by ANDRA (France), NUMO (Japan), NAGRA (Switzerland) and ENRESA (Spain) in May 2003, after the EDRAM meeting held in Valencia to study the situation in the different EDRAM member countries regarding the treatment of radioactive waste ownership and management of long-term liabilities.

The Department of Energy (DOE), pursuant to the Atomic Energy Act of 1954
as amended, the Energy Reorganization Act of 1974, the Department of Energy
Organization Act of 1977, and the Nuclear Waste Policy Act of 1982 (the Act),
has the responsibility to provide for the disposal of high-level radioactive
waste and spent nuclear fuel.* The DOE selected mined geologic repositories
as the preferred means for the disposal of commercially generated high-level
radioactive waste and spent fuel (Federal Register, Vol. 46, p. 26677, May 14,