This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development (WPD) department to provide a probabilistic evaluation of the potential for criticality of fissile material which has been transported from a geologic repository containing breached waste packages of commercial spent nuclear fuel (SNF). This analysis is part of a continuing investigation of the probability of criticality resulting from the emplacement of spent nuclear fuel in a geologic repository.

The purpose of the material degradation and release (MDR) model is to predict the fate of the waste package materials, specifically the retention or mobilization of the radionuclides and the neutron-absorbing material as a function of time after the breach of a waste package during the 10,000 years after repository closure. The output of this model is used directly to assess the potential for a criticality event inside the waste package due to the retention of the radionuclides combined with a loss of the neutron-absorbing material.

The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating long-term waste package performance in the total system performance assessment (TSPA). The waste package design for the license application is a double-wall waste package placed underneath a protective drip shield (SNL 2007 [DIRS 179394]; SNL 2007 [DIRS 179354]). The WPOB will be constructed of Alloy 22 (UNS N06022) (SNL 2007 [DIRS 179567], Section 4.1.1.6), a highly corrosion-resistant nickel-based alloy.

The purpose of this report is to document and validate the external accumulation model that predicts accumulation of fissile materials in the invert, fractures and lithophysae in the rock beneath a degrading waste package containing spent nuclear fuel (SNF) in the monitored geologic repository at Yucca Mountain. (Lithophysae are hollow, bubblelike structures in the rock composed of concentric shells of finely crystalline alkali feldspar, quartz, and other materials (Bates and Jackson 1984 [DIRS 128109], p.

Stress corrosion cracking (SCC) is one of the most common corrosion-related causes for premature breach of metal structural components. SCC is the initiation and propagation of cracks in structural components due to three factors that must be present simultaneously (Jones 1992 [DIRS 169906], Section 8.1): metallurgical susceptibility, critical environment, and sustained tensile stresses.

This report was developed in accordance with the requirements in Technical Work Plan for Postclosure Waste Form Modeling (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA).

In this study, the long-term geochemical behavior of waste package (WP), containing Pu-ceramic, was modeled. The ceramic under consideration contains Ti, U, Pu, Gd and Hf in a pyrochlore structure; the Gd and Hf stabilize the mineral structure, but are also intended to provide criticality control. The specific study objectives were to determine:
1) the extent to which criticality control material, suggested for this WP design, will remain in the WP after corrosion/dissolution of the initial package configuration (such that it can be effective in preventing criticality), and

The Disposal Criticality Analysis Methodology Topical Report (Reference 1) states that the accuracy of the criticality analysis methodology (MCNP Monte Carlo code and cross-section data) designated to assess the potential for criticality of various configurations in the Yucca Mountain proposed repository is established by evaluating appropriately selected benchmark critical experiments.

This study is prepared by the Mined Geologic Disposal System (MODS) Waste Package Development Department (WPDD) to provide input to a separate evaluation on the probablility of criticality in the far- field environment. These calculations are performed in sufficient detail to provide conservatively bounding configurations to support separate probabilistic analyses.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

The repository design includes a drip shield (BSC 2004 [DIRS 168489]) that provides protection for the waste package both as a barrier to seepage water contact and a physical barrier to potential rockfall.
The purpose of the process-level models developed in this report is to model dry oxidation, general corrosion, and localized corrosion of the drip shield plate material, which is made of Ti Grade 7. This document is prepared ·according to Technical Work Plan For: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package (BSC 2004 [DIRS 171583]).

The purpose of this analysis is to evaluate the types of defects or imperfections that could occur in a waste package or a drip shield and potentially lead to its early failure, and to estimate a probability of undetected occurrence for each type. An early failure is defined as the through-wall penetration of a waste package or drip shield due to manufacturing or handling-induced defects, at a time earlier than would be predicted by mechanistic degradation models for a defect-free waste package or drip shield.

Hydrogen-induced cracking is characterized by the decreased ductility and fracture toughness of a material due to the absorption of atomic hydrogen in the metal crystal lattice. Corrosion is the source of hydrogen generation. For the current design of the engineered barrier without backfill, hydrogen-induced cracking may be a concern because the titanium drip shield can be galvanically coupled to rock bolts (or wire mesh), which may fall onto the drip shield, thereby creating conditions for hydrogen production by electrochemical reaction.

The purpose of this report is to evaluate the potential for penetration of the Alloy 22 (UNS N06022) waste package outer barrier by localized corrosion due to the deliquescence of soluble constituents in dust present on waste package surfaces. The results support a recommendation to exclude deliquescence-induced localized corrosion (pitting or crevice corrosion) of the outer barrier from the total system performance assessment for the license application (TSPA-LA).

This report presents the analyses and results for the potential occurrence of external criticality events which could result from plutonium waste forms emplaced in a geologic repository similar to the one being developed at Yucca Mountain. The analyses evaluate both the MOX spent fuel and the immobilized plutonium waste forms in a repository if the waste package has degraded and if the fissile material has migrated to the invert and out into the far-field.